Yes. There are many Ignition hot circuits under the hood... most of which can be found underneath the UhBEC... "Underhood Body Electrical Center"... basically, the power distribution center, aka the main fuse box.
Remove negative lead off of battery, cover negative battery terminal, and wait 10 minutes.
If you unfasten that fuse box and turn it over (as best as you can, it is hard to turn with all the wires attached) you will find an overwhelming amount of ignition hot wires. They are all known to be good, otherwise the car wouldn't run!
You will notice right away that the many, if not the majority of wires that are PINK in color. Generally speaking, pink is the color GM most often uses for ignition hot circuits on our GMT800 vehicles. GM's term for these pink wires is "Ignition 1 Voltage."
A wiring diagram for your year, engine, and options is STRONGLY RECOMMENDED. I have a 2500 YXL similar to yours, but I have a different engine, and different electrical options, so the circuit arrangement in my UhBEC might differ from yours. With that being said, I found Ignition 1 voltage in 19 different cavities within the first 2 connectors alone, and there are 9 connectors under the box.
Connector C1: Cavities A6, A9, D10, F1, F5, F6
Connector C2: Cavities A9, A12, B9, B10, C10, D8, D9, D10, E6, E7, E10, F8, F9
Connector C3: (anyway, you get the idea)
The presence or lack thereof of Ignition 1 in these cavities is very much equipment and option dependent. The wiring diagrams indicate the RPO codes where these circuits might be expected to be found in.
Then, it will take personal judgement to decide what kind of load you are adding, and what components are already on the circuit you are sharing that might be affected by your addition. i'm assuming you are just adding a trigger voltage relay, which isn't much of a load, but all the same I probably wouldn't chose to splice into the Ignition 1 source to say, the ABS module.
A few years ago, I needed an ignition hot to trigger a factory relay that I added for a second battery. After considerable thinking about which Ignition 1 source to splice into in the UhBEC, I ultimately decided to follow the factory wiring diagram for RPO code TP2 exactly, which involved passing a new Ignition 1 wire from the LhBEC (Left hand Body Electrical Center) under the left hand side of the dash inside the cab, through the fire wall, into the UhBEC. Seemed kind of silly, and was no doubt unnecessary, since there were SO MANY Ignition 1 circuits to chose from that were already RIGHT THERE, but I wanted the factory circuits I added to exactly match the diagram in that instance.