Dexron VI IS NOT a pao synthetic. Its what is referred to as a Group III base stock, PAO is Group IV
Nothing GM branded is PAO.
Yes, I was thinking of the LV-ATF version, aka HP. The spec for it is simply titled Low Viscosity ATF https://standards.globalspec.com/std/13112609/GMW16954
The kinematic viscosity specs are the same as Dexron VI, but the LV (aka HP) reduces the Brookfield at -40 from 15,000 to 8,000.
Looking at the chart here, I think you can see why the spec was only able to be met by including some PAO when the spec first came out. I believe that GM revised the spec so that the much cheaper Group III could be used. I'm still pretty sure that it was actually Group 4 based fluid, when the LV (GM HP-ATF) was first introduced.
There are still plenty of GM licensed (branded) ATF today that include PAO. GM doesn't actually produce the ATF, they just license others to make it, and unlike companies like ZF, which typically only licenses one manufacturer at a time for a specific fluid, GM will allow more than one.
Regardless of what is actually licensed in a particular bottle, I still argue that it is pretty difficult to make a 6 cSt ATF (which is what both VI and LV-HP are spec'd at) which doesn't shear below 5.5 cSt in a 6000 lb truck/suv during the 100K mile life, without blending a lot of PAO.