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Congrats on the truck. You’re right about the cold. There’s a slight chance using the heater on max for both the front and rear a/c may have burped some air out of the system and made room for more.
Looks to be a little overfilled which is why you smell it due to expanding over into the overflow line. Check it when cold and find the cold mark on the bottle. If over then remove enough to get to the cold line