you can swap the entire vortec powertrain system along with sensors, exhaust, fuel system and computer equipment, engine compartment a/c equipment to upgrade the '95 with more hp and torque then the tbi has. you can take just about all of the interior, and i say just about because a few things you will not move over, and clean up the vortec vehicle. that would be easier if you did not have to move the dash as well.you can take the vortec short block and put the tbi heads on it and replace the older block in the '95. mani are out there to but may require extra egr oand/or cooling system by-pass work.
However run a compression test on the cylinders first. what kind of before/after pressure we talking about. how quick was the change? when the engine is running the should be no way raw fuel should get in the cooling system. exhaust fumes yes if a head or gasket is cracked. what do all the fluids look like? look of spark plugs as well please.