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Mmm, not sure why you believe the brand of gas will make any difference in mpg.
Most gas stations within an area, regardless of brand, are serviced by the same pipelines and more often than not are served by the same distributor. Different companies do add additives but that is heavily regulated by the EPA so they basically all have the same additives marketed under different names.
My suspicion is that any fluctuation you might observe will be due to driving variance more than whose fuel you use.
I always use shell 89,91 and I can say it's good..
My eyefour..
I used to think the same thing until Justin did the tune on our Burban and noted that the octane gas we were using from BP wasn't burning how it should be.