what ecm is in that truck? have you looked into hptuners or efi live? you'd have to look it up, but some gm ecm's can pretty easily run ethanol sensor and have the tables already in them, just gotta add the sensor and enable it. yours might be one. if you have e85 local and drive often, it would pay for itself.
even if not, you can adjust for it some to not set codes. at least to the point you run out of injector. if you're going to play around with it without tuning, have something to keep an eye on short term and long term trims. as long as you're part throttle not in PE enrichment mode, your trims should add some fuel. been years but I believe even your narrow band o2's still target stoich for whatever fuel they see. they don't what it is.
I only run e85 thru mine stuff right now as a cleaner.. I've seen it clean up the top of pistons better than any cleaner. I'm with you, especially if you don't have cats. it smells much better. I've gotten so sick of smelling like gas fumes I've put cats back on everything. even my motorcycle. I swapped the exhaust on it years ago and tossed the stock with cat in the attic. few years back I put it back on.. was tired of the noise and the smell.
be careful if you find some av gas, most of it says low lead but its low lead for av gas. it's really high for the car world. if you do have cats, it's said to plug them up pretty quickly.
have guys with the 6.2 that wants 93 tried lowering the timing to run 87? wasn't a big deal when it was 30 cents more, but now it's a dollar more. kinda annoying if you don't drive it hard enough to notice a few extra hp.
even my ls3 c6 it's annoying to need 93 for highway trips, I was going to copy the low octane map into the high octane map and flash it for my next trip run 87 and then flash it back. when I got there. but I ended up trailering instead.
I was looking for a 6.2, kinda happy I found this 6.0 instead that seems perfectly happy daily and towing on 87.