Be careful with that description of the vent valve circuit. 12v is applied when the key is on; when the ignition is off, no voltage is applied and the valve should be open. Having it commanded on with the ignition off would introduce a full time draw on the battery.
The purge valve is somewhat the opposite; when the ignition is off, the valve is closed. When the ignition is on, the purge valve is closed until the system commands it open to purge the canister of the fumes.
You have a 12v source on the truck; either use the scan tool to command the vent valve open/closed, or remove it from the truck and use small jumpers at the battery. I would not apply an external 12v source to the valve while it's still in-circuit.