You're 100% sure it shifts from 4th (OD) to 3rd when you hold the throttle steady and manually shift it? When in OD ("D" on indicator) and you you give it more throttle, it may just be the torque converter clutch unlocking and allowing the RPM to jump but it's not actually downshifting. It should still accelerate, slowly, but still.
EVAP stuff being clogged wouldn't affect the fuel supply unless the tank vent was clogged and the resulting siphoning effect was holding back the fuel. You'd have a rushing air sound when you unscrewed the gas cap, though. Also, leaving the cap loose would fix this if a clogged vent was the actual problem. Your poor fuel pump, though!
You could borrow a fuel pressure gauge from Autozone for free and test that at least. On an S10 I was working on, I pinned the gauge to the windshield with the wiper and ran the hose betwen the hood and cowl to the fuel line so I could watch the pressure as I drove.